Carbonic Anhydrase (CA)
For a primer on COS and its interaction with leaf carbonic anhydrase, Seibt et al. 2010 and Stimler et al. 2011 offer an excellent summary of the overall mechanisms. The literature here is divided into Leaf Physiology and Soil Microorganisms.
Carbonic Anhydrase/Leaf Physiology
Stimler, K., Berry, J. A., Montzka, S. A. and Yakir, D.: Association between Carbonyl Sulfide Uptake and 18Δ during Gas Exchange in C3 and C4 Leaves, Plant Physiol., 157(1), 509–517, doi:10.1104/pp.111.176578, 2011.
Seibt, U., Kesselmeier, J., Sandoval-Soto, L., Kuhn, U. and Berry, J. A.: A kinetic analysis of leaf uptake of COS and its relation to transpiration, photosynthesis and carbon isotope fractionation, Biogeosciences, 7(1), 333–341, doi:10.5194/bg-7-333-2010, 2010.
Stimler, K., Montzka, S. A., Berry, J. A., Rudich, Y. and Yakir, D.: Relationships between carbonyl sulfide (COS) and CO2 during leaf gas exchange, New Phytol., 186(4), 869–878, doi:10.1111/j.1469-8137.2010.03218.x, 2010.
Yonemura, S., Sandoval-Soto, L., Kesselmeier, J., Kuhn, U., Von Hobe, M., Yakir, D. and Kawashima, S.: Uptake of carbonyl sulfide (COS) and emission of dimethyl sulfide (DMS) by plants, Phyton, 45(4), 17–24, 2005.
Schenk, S., Kesselmeier, J. and Anders, E.: How Does the Exchange of One Oxygen Atom with Sulfur Affect the Catalytic Cycle of Carbonic Anhydrase?, Chem. – Eur. J., 10(12), 3091–3105, doi:10.1002/chem.200305754, 2004.
Protoschill-Krebs, G., Wilhelm, C. and Kesselmeier, J.: Consumption of carbonyl sulphide (COS) by higher plant carbonic anhydrase (CA), Atmos. Environ., 30(18), 3151–3156, doi:10.1016/1352-2310(96)00026-X, 1996.
Protoschill-Krebs, G. and Kesselmeier, J.: Enzymatic pathways for the consumption of carbonyl sulphide (COS) by higher plants, Bot. Acta, 105(3), 206–212, 1992.
Micro-organisms
Ogawa, T., Noguchi, K., Saito, M., Nagahata, Y., Kato, H., Ohtaki, A., Nakayama, H., Dohmae, N., Matsushita, Y., Odaka, M., Yohda, M., Nyunoya, H. and Katayama, Y.: Carbonyl Sulfide Hydrolase from Thiobacillus thioparus Strain THI115 Is One of the β-Carbonic Anhydrase Family Enzymes, J. Am. Chem. Soc., 135(10), 3818–3825, doi:10.1021/ja307735e, 2013.
Kato, H., Saito, M., Nagahata, Y. and Katayama, Y.: Degradation of ambient carbonyl sulfide by Mycobacterium spp. in soil, Microbiology, 154(1), 249–255, doi:10.1099/mic.0.2007/011213-0, 2008.
Notni, J., Schenk, S., Protoschill‐Krebs, G., Kesselmeier, J. and Anders, E.: The Missing Link in COS Metabolism: A Model Study on the Reactivation of Carbonic Anhydrase from its Hydrosulfide Analogue, ChemBioChem, 8(5), 530–536, doi:10.1002/cbic.200600436, 2007.
Conrad, R.: Soil microorganisms as controllers of atmospheric trace gases (H2, CO, CH4, OCS, N2O, and NO)., Microbiol. Rev., 60(4), 609–640, 1996.
Carbonic Anhydrase/Leaf Physiology
Stimler, K., Berry, J. A., Montzka, S. A. and Yakir, D.: Association between Carbonyl Sulfide Uptake and 18Δ during Gas Exchange in C3 and C4 Leaves, Plant Physiol., 157(1), 509–517, doi:10.1104/pp.111.176578, 2011.
Seibt, U., Kesselmeier, J., Sandoval-Soto, L., Kuhn, U. and Berry, J. A.: A kinetic analysis of leaf uptake of COS and its relation to transpiration, photosynthesis and carbon isotope fractionation, Biogeosciences, 7(1), 333–341, doi:10.5194/bg-7-333-2010, 2010.
Stimler, K., Montzka, S. A., Berry, J. A., Rudich, Y. and Yakir, D.: Relationships between carbonyl sulfide (COS) and CO2 during leaf gas exchange, New Phytol., 186(4), 869–878, doi:10.1111/j.1469-8137.2010.03218.x, 2010.
Yonemura, S., Sandoval-Soto, L., Kesselmeier, J., Kuhn, U., Von Hobe, M., Yakir, D. and Kawashima, S.: Uptake of carbonyl sulfide (COS) and emission of dimethyl sulfide (DMS) by plants, Phyton, 45(4), 17–24, 2005.
Schenk, S., Kesselmeier, J. and Anders, E.: How Does the Exchange of One Oxygen Atom with Sulfur Affect the Catalytic Cycle of Carbonic Anhydrase?, Chem. – Eur. J., 10(12), 3091–3105, doi:10.1002/chem.200305754, 2004.
Protoschill-Krebs, G., Wilhelm, C. and Kesselmeier, J.: Consumption of carbonyl sulphide (COS) by higher plant carbonic anhydrase (CA), Atmos. Environ., 30(18), 3151–3156, doi:10.1016/1352-2310(96)00026-X, 1996.
Protoschill-Krebs, G. and Kesselmeier, J.: Enzymatic pathways for the consumption of carbonyl sulphide (COS) by higher plants, Bot. Acta, 105(3), 206–212, 1992.
Micro-organisms
Ogawa, T., Noguchi, K., Saito, M., Nagahata, Y., Kato, H., Ohtaki, A., Nakayama, H., Dohmae, N., Matsushita, Y., Odaka, M., Yohda, M., Nyunoya, H. and Katayama, Y.: Carbonyl Sulfide Hydrolase from Thiobacillus thioparus Strain THI115 Is One of the β-Carbonic Anhydrase Family Enzymes, J. Am. Chem. Soc., 135(10), 3818–3825, doi:10.1021/ja307735e, 2013.
Kato, H., Saito, M., Nagahata, Y. and Katayama, Y.: Degradation of ambient carbonyl sulfide by Mycobacterium spp. in soil, Microbiology, 154(1), 249–255, doi:10.1099/mic.0.2007/011213-0, 2008.
Notni, J., Schenk, S., Protoschill‐Krebs, G., Kesselmeier, J. and Anders, E.: The Missing Link in COS Metabolism: A Model Study on the Reactivation of Carbonic Anhydrase from its Hydrosulfide Analogue, ChemBioChem, 8(5), 530–536, doi:10.1002/cbic.200600436, 2007.
Conrad, R.: Soil microorganisms as controllers of atmospheric trace gases (H2, CO, CH4, OCS, N2O, and NO)., Microbiol. Rev., 60(4), 609–640, 1996.